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Beilstein J. Org. Chem. 2017, 13, 1857–1865, doi:10.3762/bjoc.13.180
Graphical Abstract
Figure 1: Mechanisms of O-GTs-catalysed glycosylation.
Figure 2: Desulfoglucosinolate biosynthesis by UGT74B1.
Figure 3: Examples of thiol-containing acceptors used in the chemo-enzymatic biosynthesis of S-glycosides cat...
Figure 4: Examples of C-glycosylated products biosynthesized by natural C-GT. Compounds showed are formed by ...
Figure 5: General mechanisms of the O-GHs-catalysed hydrolysis.
Figure 6: Neighbouring group participation mechanism of retaining the O-GHs-catalysed hydrolysis.
Figure 7: Mechanism of the thioligases.
Figure 8: Examples of thiol acceptors utilized with GHs.